Транс фект


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Однако в конце х и особенно в х годах за рубежом динамическое проявление данного явления стали называть транс-эффектом. На этой странице вы можете бесплатно скачать и слушать онлайн песню Транс Эффект исполнителя Dj Лёш@ или смотреть видео клип.

In addition to this kinetic trans effect , trans ligands also have an influence on the ground state of the molecule, the most notable ones being bond lengths and stability. By using this site, you agree to the Terms of Use and Privacy Policy. From Wikipedia, the free encyclopedia.

Транс фект

The classic example of the trans effect is the synthesis of cisplatin and its trans isomer. Stretching by as much as 0. Views Read Edit View history.

Транс фект

Views Read Edit View history. Some authors prefer the term trans influence to distinguish it from the kinetic effect, [2] while others use more specific terms such as structural trans effect or thermodynamic trans effect. By using this site, you agree to the Terms of Use and Privacy Policy.

In addition to this kinetic trans effect , trans ligands also have an influence on the ground state of the molecule, the most notable ones being bond lengths and stability. Retrieved from " https: The classic example of the trans effect is the synthesis of cisplatin and its trans isomer.

Retrieved from " https: Trans-effects in octahedral transition metal complexes. Views Read Edit View history. The mononitrites of bivalent platinum. The classic example of the trans effect is the synthesis of cisplatin and its trans isomer.

Coordination Chemistry Reviews , , The classic example of the trans effect is the synthesis of cisplatin and its trans isomer. The Organometallic Chemistry of the Transition Metals 4th ed.

From Wikipedia, the free encyclopedia. The classic example of the trans effect is the synthesis of cisplatin and its trans isomer. Coordination Chemistry Reviews , , The third and final equatorial site is occupied by the trans ligand, so the net result is that the kinetically favored product is the one in which the ligand trans to the one with the largest trans effect is eliminated.

A cis influence can also be observed, but is smaller than the trans influence. By using this site, you agree to the Terms of Use and Privacy Policy.

Coordination Chemistry Reviews , , The third and final equatorial site is occupied by the trans ligand, so the net result is that the kinetically favored product is the one in which the ligand trans to the one with the largest trans effect is eliminated.

Retrieved from " https:

Retrieved from " https: The intensity of the trans effect as measured by the increase in rate of substitution of the trans ligand follows this sequence:. From Wikipedia, the free encyclopedia. The discovery of the trans effect is attributed to Ilya Ilich Chernyaev , [3] who recognized it and gave it a name in

The relative importance of the cis and trans influences depends on the formal electron configuration of the metal center, and explanations have been proposed based on the involvement of the atomic orbitals. Some authors prefer the term trans influence to distinguish it from the kinetic effect, [2] while others use more specific terms such as structural trans effect or thermodynamic trans effect.

In addition to this kinetic trans effect , trans ligands also have an influence on the ground state of the molecule, the most notable ones being bond lengths and stability. The second equatorial position is occupied by the incoming ligand; due to the principle of microscopic reversibility , the departing ligand must also leave from an equatorial position.

From Wikipedia, the free encyclopedia. It is attributed to electronic effects and it is most notable in square planar complexes , although it can also be observed for octahedral complexes. Retrieved from " https: The discovery of the trans effect is attributed to Ilya Ilich Chernyaev , [3] who recognized it and gave it a name in The third and final equatorial site is occupied by the trans ligand, so the net result is that the kinetically favored product is the one in which the ligand trans to the one with the largest trans effect is eliminated.

The classic example of the trans effect is the synthesis of cisplatin and its trans isomer. This page was last edited on 3 December , at It is attributed to electronic effects and it is most notable in square planar complexes , although it can also be observed for octahedral complexes. The intensity of the trans effect as measured by the increase in rate of substitution of the trans ligand follows this sequence:.

The mononitrites of bivalent platinum.

In addition to this kinetic trans effect , trans ligands also have an influence on the ground state of the molecule, the most notable ones being bond lengths and stability. Views Read Edit View history. The intensity of the trans effect as measured by the increase in rate of substitution of the trans ligand follows this sequence:.

Stretching by as much as 0. The classic example of the trans effect is the synthesis of cisplatin and its trans isomer. The second equatorial position is occupied by the incoming ligand; due to the principle of microscopic reversibility , the departing ligand must also leave from an equatorial position.

The Organometallic Chemistry of the Transition Metals 4th ed.

The intensity of the trans effect as measured by the increase in rate of substitution of the trans ligand follows this sequence:. In other projects Wikimedia Commons. By using this site, you agree to the Terms of Use and Privacy Policy. The discovery of the trans effect is attributed to Ilya Ilich Chernyaev , [3] who recognized it and gave it a name in It is attributed to electronic effects and it is most notable in square planar complexes , although it can also be observed for octahedral complexes.

The relative importance of the cis and trans influences depends on the formal electron configuration of the metal center, and explanations have been proposed based on the involvement of the atomic orbitals.



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